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- Title
2,2-Bis(phenylsulfonyl)ethyl sulfides as efficient precursors of sulfenic acids.
- Authors
Aversa, Maria C.; Barattucci, Anna; Bonaccorsi, Paola; Rollin, Patrick; Tatibouët, Arnaud
- Abstract
The use of 2,2-bis(phenylsulfonyl)ethyl sulfides as efficient precursors of sulfenic acids is reported. These starting compounds, carrying both sulfone and sulfide residues, are obtained in one step from commercially available thiols and 1,1-bis(phenylsulfonyl)ethylene. Mild decomposition of the derived 2,2-bis(phenylsulfonyl)ethyl sulfoxides to sulfenic acids, in the presence of suitable acceptors, opens the way to the generation of a wide library of new sulfoxides not easily accessible through different synthetic pathways.
- Subjects
ETHYL chloride; SULFENIC acids; SULFIDES; BIOACTIVE compounds; PROTEIN precursors; THIOLS; SULFONES; ETHYLENE; SULFOXIDES
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2009, p187
- ISSN
1551-7004
- Publication type
Article