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- Title
Condensations based on 5‐(indol‐3‐yl)‐pyrrolidin‐2‐thiones.
- Authors
Sadovoy, Andrey V.; Kattsyna, Veronica V.; Protopopova, Polina S.; Nelyubina, Yulia V.; Pavlov, Alexander A.; Kochetkov, Konstantin A.; Sviridova, Lyudmila A.
- Abstract
New activated indolylpyrrolidones—their methylthiopyrrolinium salts—in the reactions with several CH‐acids were studied. 2‐Nitromethylene‐ and 2‐dicyanomethyleneindolylpyrrolidines were obtained from 5‐indolyl‐2‐methylthiopyrrolinium salts with good yields. The reduction in these nitro compounds yields the respective aminomethylpyrolidines. The rigid structure of the starting compounds has significant stereoelectronic requirements of nucleophilic agents.
- Subjects
PYRROLIDINE; THIONES; NITROMETHYLENE compounds; NITRO compounds; STEREOELECTRONIC control; NUCLEOPHILES
- Publication
Heteroatom Chemistry, 2018, Vol 29, Issue 4, pN.PAG
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/hc.21451