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- Title
Iron pentacarbonyl, efficient promoter of aromatic compounds alkylation with bromoadamantane.
- Authors
Ambartsumyan, A.; Vasil'eva, T.; Chakhovskaya, O.; Mysova, N.; Kochetkov, K.
- Abstract
The article presents a study that examines the initiating effects of iron pentacarbonyl using halogen containing addend the sterically hindered 1-bromoadamantane. It describes the method of the study that adds 1-bromoadamantane (I) to pentafluorobenzaldehyde by the type of Zaitsev-Barbier reaction in the presence of iron pentacarbonyl. It outlines the result of the study which shows that organic reagents were purified by distillation or recrystallization.
- Subjects
HALOGEN compounds; RECRYSTALLIZATION (Metallurgy); AROMATIC compounds; ALKYLATION; ZAITSEV rule
- Publication
Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 5, p752
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428014050236