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- Title
Structure and rearrangements of 3-Iso(thio,seleno)cyanato-1,2,3-triarylcyclopropenes.
- Authors
Mikhailov, I. E.; Dushenko, G. A.; Reck, G.; Schulz, B.; Mikhailova, O. I.; Minkin, V. I.
- Abstract
A series of new fluctional 3-iso(thio,seleno)cyanato-1,2,3-triarylcyclopropenes was synthesized. The structure of compounds was proved by 1H and 13C NMR, IR, and mass spectra, and that of 3-(1,2,3-triphenylcyclopropenyl) isothiocycnate was confirmed by X-ray crystallography. In compounds under consideration by means of 1H and 13C NMR was discovered and investigated a fast reversible migration of isocyanato, isothiocyanato, and isoselenocyanato groups along the perimeter of the theree-membered ring proceeding according to the dissociation-recombination mechanism.
- Subjects
CHEMICAL structure; X-ray crystallography; MASS spectrometry; PHYSICAL &; theoretical chemistry; CHEMISTRY
- Publication
Russian Journal of Organic Chemistry, 2006, Vol 42, Issue 11, p1630
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428006110066