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- Title
Study of the Metal Exchange Reaction of Cadmium(II) 5,15-Dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with d-Metal Salts in Organic Solvents.
- Authors
Zvezdina, S. V.; Chizhova, N. V.; Mamardashvili, N. Z.
- Abstract
The kinetics of the metal exchange reactions of cadmium(II) 5,15-dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with copper(II) and zinc(II) chlorides in DMF and DMSO were investigated by the spectrophotometric method. The kinetic parameters of the metal exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed. The effect of the solvent and solvate salt nature on the rate of the metal exchange reaction was revealed.
- Subjects
ORGANIC solvents; CADMIUM; EXCHANGE reactions; METALS; FOREIGN exchange rates; SALTS
- Publication
Russian Journal of General Chemistry, 2022, Vol 92, Issue 2, p256
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363222020153