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- Title
Crystal and magnetic structures of hexagonal YMnO<sub>3</sub>.
- Authors
Howard, Christopher J.; Campbell, Branton J.; Stokes, Harold T.; Carpenter, Michael A.; Thomson, Richard I.
- Abstract
The available data on the structural and magnetic transitions in multiferroic hexagonal YMnO3 have been reviewed, first making use of the computer programs from the group theoretical ISOTROPY software suite to list possible crystal and magnetic structures, then taking into account the capability of neutron diffraction and other physical methods to distinguish them. This leads to a clear view of the transformation sequence, as follows. Hexagonal YMnO3 is paraelectric in P63/ mmc at elevated temperatures, and undergoes a single structural transition on cooling through 1250 K to a ferrielectric phase in P63 cm that is retained through room temperature. At a much lower temperature, 70 K, there is a magnetic transition from paramagnetic to a triangular antiferromagnetic arrangement, most likely with symmetry P63′ cm′. Comment is made on the unusual coupling of ferroelectric and magnetic domains reported to occur in this material, as well as on the so-called `giant magneto-elastic' effect.
- Subjects
CRYSTAL structure; MULTIFERROIC materials; ISOTROPY subgroups; NEUTRON diffraction; MAGNETIC transitions
- Publication
Acta Crystallographica Section B: Structural Science, Crystal Engineering & Materials, 2013, Vol 69, Issue 6, p534
- ISSN
2052-5192
- Publication type
Article
- DOI
10.1107/S205251921302993X