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- Title
(p‐(Diphenylarsino)phenyl)diphenylphosphine as a Novel Template for Heterodinuclear Complexes.
- Authors
Akioka, Ippei; Sumida, Akifumi; Urushizaki, Aya; Imoto, Hiroaki; Naka, Kensuke
- Abstract
Phosphorus and arsenic have different coordination ability to Lewis acids, though they belong to 15 group. Utilizing the difference, we designed a novel ligand, (p‐(diphenylarsino)phenyl)diphenylphosphine, in which diphenylphosphine and diphenylarsine units are combined through a p‐phenylene linker, as a template to arrange Lewis acids. The phosphorus atom exhibited superior coordination ability to the arsenic one. NMR studies revealed that BH3, AuCl, and PtCl2 were preferentially coordinated by the phosphorus atom. Sequential addition of these Lewis acids realized precise arrangement on the template ligand.
- Subjects
DIPHENYLPHOSPHINE; LEWIS acids; ARSENIC; PHOSPHORUS
- Publication
Asian Journal of Organic Chemistry, 2021, Vol 10, Issue 2, p375
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202000612