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- Title
Azo-containing core-fluorinated hydroxyethylated diamines -- monomers for the synthesis of polymers with nonlinear optical properties.
- Authors
Shevchenko, V. V.; Sidorenko, A. V.; Tkachenko, I. M.; Shekera, O. V.
- Abstract
By diazotization of isomeric fluorinated diamines following the azocoupling with 2 - [ethyl(phenyl)amino]ethanol hydroxyethylated diamines were synthesized, combining in their composition azo-groups and fragments of tetrafluorobenzene and octafluorobiphenyl. The values of their molecular hyperpolarizability are calculated and the relationship between the chemical structure and nonlinear optical properties of fluorinated azo-containing chromophores is established.
- Subjects
DIAMINES; MONOMERS; POLYMERIZATION; OPTICAL properties; DIAZOTIZATION; CHROMOPHORES
- Publication
Polymer Journal / Polymernyi Zhurnal (18181724), 2013, Vol 35, Issue 3, p304
- ISSN
1818-1724
- Publication type
Article