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- Title
Reductive Retrocyclization of a Mangana(II)cyclopentasilane to Form Manganese(0) Bis(η<sup>2</sup>‐disilene) Complexes.
- Authors
Kawabuchi, Yosuke; Suzuki, Takuma; Wada, Yoshimasa; Sunada, Yusuke
- Abstract
Ligand‐exchange reactions on a mangana(II)cyclopentasilane complex that contains two THF ligands with aryl isocyanides led to the formation of manganese(0) bis(η2‐disilene) complexes via a retrocyclization. In stark contrast, ligand‐exchange reactions with CNtBu, an N‐heterocyclic carbene, or pyridine‐based ligands furnished manganese(II) complexes wherein the manganacyclopentasilane framework remained intact. The thermolysis of the obtained bis(η2‐disilene) complex in the presence of mesityl isocyanide led to the formation of a cyclotetrasilane via the formal dimerization of the two η2‐disilene moieties. The insertion of a mesityl isocyanide into the Mn−Siβ bond results in the formation of a manganese(II) complex supported by a [SiCSi]‐type tridentate ligand scaffold.
- Subjects
MANGANESE; ISOCYANIDES; THERMOLYSIS; DIMERIZATION; LIGANDS (Chemistry); RING formation (Chemistry); LIGAND exchange reactions
- Publication
Angewandte Chemie, 2024, Vol 136, Issue 15, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202319804