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- Title
Syntheses, single-crystal structure determination, and Raman spectra of Rb[C(CN)<sub>3</sub>] and Cs[C(CN)<sub>3</sub>].
- Authors
Reckeweg, Olaf; Schulz, Armin; DiSalvo, Francis J.
- Abstract
Extracting residues of an aqueous solutions containing equimolar amounts of K[C(CN)3] and RbF or CsF, respectively, with absolute ethanol, yields triangular, transparent colorless crystals of Rb[C(CN)3] and Cs[C(CN)3] after the ethanol was allowed to evaporate. The compounds are isotypic and crystallize isopointal to calcite in space group R3̅c (no. 167) with the cell parameters a=809.9(1) and c=1461.3(3) pm and a=843.29(9) and c=1459.9(2) pm, respectively. Single crystals were used to record the Raman spectra of the title compounds.
- Subjects
AQUEOUS solutions; ETHANOL; CHEMICALS; PARAMETERS (Statistics); RAMAN spectra
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2015, Vol 70, Issue 2, p151
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2014-0241