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- Title
Reaction of tellurium with dichloromethane in the system hydrazine hydrate-alkali.
- Authors
Levanova, E. P.; Grabel'nykh, V. A.; Russavskaya, N. V.; Klyba, L. V.; Albanov, A. I.; Korchevin, N. A.
- Abstract
Tellurium reacts with dichloromethane in the system hydrazine hydrate-alkali substituting one chlorine atom by tellurium whereas the second chlorine atom undergoes reductive substitution by hydrogen leading to the formation of methyltellanyl derivatives. Tentative mechanism of reduction is discussed. The discovered reaction allows the preparation of organotellurium compounds containing the MeTe group, including those involving other chalcogens.
- Subjects
TELLURIUM; DICHLOROMETHANE; HYDRAZINE; HYDRATES; HYDROGEN; ORGANOTELLURIUM compounds; CHALCOGENS
- Publication
Russian Journal of General Chemistry, 2009, Vol 79, Issue 11, p2321
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363209110073