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- Title
Industrial azomethine nickel complex pigments. Four crystal structures from X-ray powder diffraction data.
- Authors
Brüning, Jürgen; Ivashevskaya, Svetlana N.; van de Streek, Jacco; Alig, Edith; Schmidt, Martin U.
- Abstract
The crystal structures of the azomethine nickel complexes Pigment Orange 68 (P.O.68, C29H18N4O3Ni), Pigment Red 257 (P.R.257, C16H4Cl8N6O2Ni), and Solvent Brown 53 (S.Br.53, C18H10N4O2Ni) were determined from powder diffraction data. The compounds are industrially used for the colouration of plastics and coatings. P.O.68 exists in two polymorphic forms, the commercial one is the α-phase. The crystal structures were solved from laboratory data using real-space methods and refined by the Rietveld method. For the Rietveld refinement of α-P.O.68, synchrotron data were employed. In all structures, the Ni2+ ion is coordinated by two N atoms and two O atoms in a square-planar geometry. Both phases of P.O.68 crystallise in P21/c, Z = 4. In both structures, the molecules form dimers via an inversion centre, with Ni-to-Ni distances of 3.606 Å (α-phase) and 3.286 Å (β-phase). The dimers are stacked into columns. Neighbouring columns are connected by hydrogen bonds: one classical N–H⋅⋅⋅O bond, and one N–H⋅⋅⋅π bond to the naphthalene moiety of a molecule in the neighbouring stack. P.R.257 crystallises in P21/c, Z = 2, with molecules on inversion centres. The molecules show a typical van der Waals packing without close Ni-Ni contacts. S.Br.53 exhibits Pbcn symmetry with Z = 8. The molecules form columns with Ni-to-Ni distances of 3.508 Å.
- Subjects
X-ray powder diffraction; CRYSTAL structure; SCHIFF bases; RIETVELD refinement; NICKEL
- Publication
Zeitschrift für Kristallographie. Crystalline Materials, 2021, Vol 236, Issue 3/4, p105
- ISSN
2194-4946
- Publication type
Article
- DOI
10.1515/zkri-2021-2005