We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivities.
- Authors
Hsu, Yu-Chen; Shen, Jiun-Shian; Lin, Bo-Chao; Chen, Wen-Ching; Chan, Yi-Tsu; Ching, Wei-Min; Yap, Glenn P. A.; Hsu, Chao-Ping; Ong, Tiow-Gan
- Abstract
The simple synthetic development of acyclic pincer bis(pyridine)carbodicarbene is depicted herein. Presented is the first isolated structural pincer carbodicarbene with a C-C-C angle of 143°, larger than the monodentate framework. More importantly, theoretical analysis showed that this carbodicarbene embodies a more allene-like character. Palladium complexes supported by this pincer ligand are active catalysts for Heck-Mizoroki and Suzuki-Miyaura coupling reactions.
- Subjects
HETEROCYCLIC compounds; PYRIDINE; PLATINUM group; CATALYMETRIC titration; POLYMER aggregates
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 8, p2450
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201406481