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- Title
Water-Based Environmentally Friendly Pesticide Formulations Based on Cyclodextrin/Pesticide Loading System.
- Authors
Xinyu Guo; Zhe Sun; Rui Zhao; Hongyi Shang; Jiangyu Liu; Yong Xu; Laihua Liu; Xuemin Wu
- Abstract
Difenoconazole (DIF) is a representative variety of broad-spectrum triazole fungicides and liposoluble pesticides. However, the water solubility of DIF is so poor that its application is limited in plant protection. In addition, the conventional formulations of DIF always contain abundant organic solvents, which may cause pollution of the environment. In this study, two DIF/cyclodextrins (CDs) inclusion complexes (ICs) were successfully prepared, which were DIF/ß-CD IC and DIF/hydroxypropyl-ß-CD IC (DIF/HP-ß-CD IC). The effect of cyclodextrins on the water solubility and the antifungal effect of liposoluble DIF pesticide were investigated. According to the phase solubility test, the molar ratio and apparent stability constant of ICs were obtained. Fourier transform infrared spectroscopy, thermal gravity analysis, X-ray diffraction and scanning electron microscopy were used systematically to characterize the formation and characteristics of ICs. The results noted that DIF successfully entered the cavities of two CDs. In addition, the antifungal effect test proved the better performance of DIF/HP-ß-CD IC, which exceeded that of DIF emulsifiable concentrate. Therefore, our study provides informative direction for the intelligent use of liposoluble pesticides with cyclodextrins to develop water-based environmentally friendly formulations.
- Subjects
PESTICIDE formulation; CYCLODEXTRINS; X-ray diffraction; FOURIER transform infrared spectroscopy; ORGANIC solvents
- Publication
Journal of Renewable Materials, 2023, Vol 11, Issue 2, p777
- ISSN
2164-6325
- Publication type
Article
- DOI
10.32604/jrm.2022.022811