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- Title
Development of a Novel Multifunctional N,P Ligand for Highly Enantioselective Palladium-Catalyzed Asymmetric Allylic Etherification of Alcohols and Silanols.
- Authors
Ye, Fei; Zheng, Zhan‐Jiang; Li, Li; Yang, Ke‐Fang; Xia, Chun‐Gu; Xu, Li‐Wen
- Abstract
CycloN2P2‐Phos! The use of the multidentate phosphine, CycloN2P2‐Phos (see graphic), which contains four heteroatoms (two nitrogen and two phosphorus atoms), in the palladium‐catalyzed asymmetric allylic etherification (AAE) of alcohols and silanols leads to excellent levels of enantioselectivity (up to 99 % ee).
- Subjects
PHOSPHINE synthesis; PALLADIUM catalysts; ALLYLIC alkylation; SILANOLS; TERTIARY amines; LIGANDS (Chemistry); ETHERIFICATION
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 46, p15452
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201303233