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- Title
Ni Oxidation State and Ligand Saturation Impact on the Capability of Octaazamacrocyclic Complexes to Bind and Reduce CO 2.
- Authors
Vénosová, Barbora; Jelemenská, Ingrid; Kožíšek, Jozef; Rapta, Peter; Zalibera, Michal; Novotný, Michal; Arion, Vladimir B.; Bučinský, Lukáš
- Abstract
Two 15-membered octaazamacrocyclic nickel(II) complexes are investigated by theoretical methods to shed light on their affinity forwards binding and reducing CO2. In the first complex 1[NiIIL]0, the octaazamacrocyclic ligand is grossly unsaturated (π-conjugated), while in the second 1[NiIILH]2+ one, the macrocycle is saturated with hydrogens. One and two-electron reductions are described using Mulliken population analysis, quantum theory of atoms in molecules, localized orbitals, and domain averaged fermi holes, including the characterization of the Ni-CCO2 bond and the oxidation state of the central Ni atom. It was found that in the [NiLH] complex, the central atom is reduced to Ni0 and/or NiI and is thus able to bind CO2 via a single σ bond. In addition, the two-electron reduced 3[NiL]2− species also shows an affinity forwards CO2.
- Subjects
OXIDATION states; ATOMS in molecules theory; CARBON dioxide; MACROCYCLIC compounds
- Publication
Molecules, 2021, Vol 26, Issue 14, p4139
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules26144139