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- Title
Synthesis and Characterization of Pyridino(1,4-H-cyclohexa-1,3-diene) Derivatives of Iron Tricarbonyl Complexes.
- Authors
ODIAKA, T. I.; AKINYELE, O. F.; ADEJORO, I. A.
- Abstract
In this synthesis, we have been able to show that, the addition of x- substituted pyridines, (X = H, 2- Me, 3- Me 4- Me, 4-NH2 and 4-N(CH3)2 to the dienyl ring of the organometallic cation, [(Fe(CO)3 (1-5- η-2-Me0C6H6)]BF4 and [(Fe(CO)3 (1-5- η-C6H7)]BF4 gives ionic substituted diene products, (X C5H4-C6H6Y (Fe(CO)3] BF4,Y=H or 2-MeO. The reaction takes place at ordinary room temperature. The resulting products were isolated and characterized.
- Subjects
PYRIDINE spectra; COMPLEX compounds spectra; IRON compounds; ORGANOMETALLIC chemistry; ORGANOMETALLIC compounds; CATIONS
- Publication
E-Journal of Chemistry, 2011, Vol 8, Issue 3, p960
- ISSN
0973-4945
- Publication type
Article
- DOI
10.1155/2011/781484