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- Title
Coordination Polymers of N, N'-di-(8-Hydroxyquinolinolyl- 5-methyl)-N, N-diethyl-1, 3-propane diamine (QEPD).
- Authors
Patel, Asha D.; Patel, Rignesh S.; Patel, Ganpat R.
- Abstract
Coordination polymers containing a novel bis(oxine) bidentate ligand, namely N,N'-di(8-hydroxyquinolinolyl-5-methyl)-N,N'-diethyl-1,3- propane diamine (QEPD) have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with N,N'-diethyl-1,2- propane diamine in the presence of a base catalyses. All of these coordination polymers and the parent ligand were characterized by elemental analyses, IR spectral and diffuse reflectance spectral studies. The thermal stability and number- average molecular weights (Mn ) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities.
- Subjects
COORDINATION polymers; MOLECULAR weights; COMPLEX compounds synthesis; PROPANEDIAMINE; INFRARED spectra; THERMOGRAVIMETRY; CONDUCTOMETRIC analysis; MAGNETIC susceptibility; SPECTRAL reflectance
- Publication
E-Journal of Chemistry, 2010, Vol 7, Issue 3, p1023
- ISSN
0973-4945
- Publication type
Article
- DOI
10.1155/2010/609494