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- Title
Two-step Hydrothermal Syntheses and Structures of Three Tantalum Oxyfluoride Compounds with [ M(phen)<sub>3</sub>]<sup>2+</sup>( M = Ru, Fe) Counter Ions.
- Authors
Yu, Lan; Ren, Zhi‐Gang; Qian, Li‐Wen; Zhu, Qin‐Yu; Bian, Guo‐Qing; Dai, Jie
- Abstract
Three tantalum oxyfluoride compounds, [Fe(phen)3][Ta2OF10] ( 1), [Fe(phen)3][Ta2OF10] ·2H2O ( 2), and [Ru(phen)3]2[Ta2OF10][TaF6]2 ( 3), were synthesized by a two-step hydrothermal method and their crystal structures were characterized by single-crystal X-ray diffraction. The unique characters of these compounds are the [ M(phen)3]2+ cations. C-H ···F interactions exist between cations and anions and O-H ···F hydrogen bonds exist between the water molecules and anions. Photocurrent measurements reveal that compound 3 is the photoelectric responsive with the moderate current intensity.
- Subjects
TANTALUM compounds; OXYFLUORIDES; COUNTER-ions; CRYSTAL structure; PHENANTHROLINE; HYDROTHERMAL synthesis; PHOTOCURRENTS
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2015, Vol 641, Issue 3/4, p704
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201400534