We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis, Structure and Thermal Decomposition of (H<sub>9</sub>O<sub>4</sub>)<sub>2</sub>[Re<sub>6</sub>S<sub>6</sub>Br<sub>8</sub>].
- Authors
Yarovoy, S. S.; Sukhikh, T. S.; Naumov, N. G.
- Abstract
The condensation of trinuclear rhenium bromide with lead sulfide yields the (H9O4)2Re6S6Br8 octahedral cluster complex isolated from the HBr/EtOH mixture in the form of the acid. (H9O4)2[Re6S6Br8] crystallizes in the P21/c space group, a = 9.2010(2) Å, b = 9.1508(2) Å, c = 17.3759(3) Å, γ = 101.817(1)°. Thermal decomposition of the complex at a moderate temperature (350 °C) results in a metastable Re6S6Br6 compound, which is not formed in the ternary Re–S–Br system at high temperatures. This compound is X-ray amorphous; its structure is determined based on the X-ray photoelectron and Raman spectroscopy data.
- Subjects
X-ray photoelectron spectroscopy; TERNARY forms; SPACE groups; TERNARY system
- Publication
Journal of Structural Chemistry, 2024, Vol 65, Issue 2, p381
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S002247662402015X