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- Title
Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub>(H<sub>2</sub>O)]Cl·H<sub>2</sub>O.
- Authors
Emel’yanov, V. A.; Baidina, I. A.; Il’in, M. A.; Gromilov, S. A.
- Abstract
The reaction between [RuNO(NH3)2(NO2)2OH] and an excess of 3 M HCl leads to denitration of the starting complex and precipitation of [Ru(NO)(NH3)2Cl3]. Crystals of the tittle complex have been obtained by evaporation of the mother liquor at ambient temperature. The crystal structure of the product has been determined. The linear nitroso group and a water molecule are coordinated in the trans positions, three nitrogen atoms from NO and NH3 ligands occupy the coordination octahedron face.
- Subjects
NITROSOAMINES; CHLORIDES; CRYSTALLIZATION; RUTHENIUM; NITROSYL chloride; X-ray diffraction
- Publication
Journal of Structural Chemistry, 2006, Vol 47, Issue 2, p380
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-006-0311-y