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- Title
Highly Crystalline Ag‐based Coordination Polymers for Efficient Photocatalytic Oxidation of Sulfides.
- Authors
Li, Yang; Cheng, Xiuyan; Jin, Yigang; Li, Ze; Sun, Yimeng; Zou, Ye; Liu, Liyao; Zhang, Jianling; Xu, Wei
- Abstract
Coordination polymers (CPs) display great potential for the development of highly active photocatalysts. Herein, we report the fabrication of a highly crystalline CP, [Ag2BTT]n (BTT=benzene‐1,2,4,5‐tetrathiol). The crystal structure of [Ag2BTT]n was resolved and its performance for photocatalytic oxidation of thioanisole was explored. [Ag2BTT]n is highly active and selective for the photo‐oxidation of sulfides to sulfoxides under mild conditions, that is, in air, at room temperature and in the absence of a sacrificial reagent, co‐catalyst or redox mediator.
- Subjects
COORDINATION polymers; PHOTOCATALYTIC oxidation; SULFOXIDES; CATALYSTS; SULFIDES; CRYSTAL structure; PHOTOCATALYSTS
- Publication
Chemistry - An Asian Journal, 2022, Vol 17, Issue 9, p1
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.202200031