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- Title
Stabilization of Tetrahedral P<sub>4</sub> and As<sub>4</sub> Molecules as Guests in Polymeric and Spherical Environments.
- Authors
Schwarzmaier, Christoph; Schindler, Andrea; Heindl, Claudia; Scheuermayer, Sabine; Peresypkina, Eugenia V.; Virovets, Alexander V.; Neumeier, Maria; Gschwind, Ruth; Scheer, Manfred
- Abstract
As you like it: [Ag(η2‐As4)2]+[pftb]− can be used to store yellow arsenic (As4). From it, As4 can be easily released to give concentrated, light‐stable solutions. These As4 solutions, and those of white phosphorus (P4), allowed molecular As4 and P4 to be encapsulated inside giant, spherical aggregates and polymeric matrices, enabling the first determination of their EE (E=P, As) bond lengths by diffraction methods.
- Subjects
TETRAHEDRAL molecules; X-ray diffraction; CHEMICAL structure; CHEMICAL reactions; MOLECULAR shapes
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 41, p10896
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201306146