We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Perovskite-like Mn<sub>2</sub>O<sub>3</sub>: A Path to New Manganites.
- Authors
Ovsyannikov, Sergey V.; Abakumov, Artem M.; Tsirlin, Alexander A.; Schnelle, Walter; Egoavil, Ricardo; Verbeeck, Jo; Van Tendeloo, Gustaaf; Glazyrin, Konstantin V.; Hanfland, Michael; Dubrovinsky, Leonid
- Abstract
Phases of the Mn2O3: Two new phases of Mn2O3—corundum‐type ε‐Mn2O3 and perovskite‐type ζ‐Mn2O3—were obtained by high‐pressure high‐temperature synthesis. Manganese atoms were found to completely occupy the A‐ and B‐positions of perovskite simultaneously. The perovskite‐type ζ‐Mn2O3 has an A‐site‐ordered perovskite structure (see picture) containing Mn in three different oxidation states (+II, +III, and +IV).
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 5, p1494
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201208553