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- Title
Harnessing Reversible Oxidative Addition: Application of Diiodinated Aromatic Compounds in the Carboiodination Process.
- Authors
Petrone, David A.; Lischka, Matthias; Lautens, Mark
- Abstract
An I for an I: Conditions for the intramolecular carboiodination and the simultaneous convergent intramolecular carboiodination/intermolecular Heck reaction of various diiodoarenes were developed. The ability of the Pd0/QPhos catalyst/ligand combination to undergo reversible oxidative addition allows these reactions to proceed well, thus increasing both the appeal and utility of this class of substrates in site‐selective cross‐coupling reactions.
- Subjects
AROMATIC compounds; ORGANIC cyclic compounds; CATALYTIC activity; PHYSICAL &; theoretical chemistry research; PALLADIUM; ALKENES
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 40, p10635
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201304923