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- Title
Driving Force for Oxygen-Atom Transfer by Heme-Thiolate Enzymes.
- Authors
Wang, Xiaoshi; Peter, Sebastian; Ullrich, René; Hofrichter, Martin; Groves, John T.
- Abstract
Absolutely: Redox potentials for three redox couples in AaeAPO‐catalyzed reactions have been measured, thus placing these heme‐thiolate reactive intermediates on an absolute energy scale for the first time. The importance of the axial thiolate ligand and the basic nature of compound II ferryl oxygen atom are discussed in terms of these redox potentials.
- Subjects
OXYGEN atom transfer reactions; ENZYMES; CHLOROPEROXIDASE; CHLORIDES; BROMIDE ions; HALIDES; CHEMICAL reactions
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 35, p9238
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201302137