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- Title
A Novel [OSSO]‐Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides.
- Authors
Della Monica, Francesco; Paradiso, Veronica; Grassi, Alfonso; Milione, Stefano; Cavallo, Luigi; Capacchione, Carmine
- Abstract
A new chromium(III) complex, bearing a bis‐thioether‐diphenolate [OSSO]‐type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.
- Subjects
CARBON dioxide; PROPYLENE carbonate; EPOXY compounds; COPOLYMERIZATION; CHROMIUM; CHROMIUM compounds
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 24, p5347
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201905455