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- Title
Reductive Cross‐Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides.
- Authors
Lansbergen, Beatrice; Tewari, Srija; Tomczyk, Ireneusz; Seemann, Maik; Buchholz, Henning Louis; Rippegarten, Mike; Cieminski, Daniel Chamier; Juliá, Fabio; Ritter, Tobias
- Abstract
We report the first reductive vinylation of alkyl iodides. The reaction uses a vinyl thianthrenium salt, a palladium catalyst, and an alkyl zinc intermediate formed in situ to trap the LnPdII(vinyl) complex formed after oxidative addition before it undergoes undesired homocoupling to form butadiene.
- Subjects
ALKYL iodide; PALLADIUM catalysts; OXIDATIVE addition; SALT; VINYLATION
- Publication
Angewandte Chemie, 2023, Vol 135, Issue 52, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202313659