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- Title
Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands.
- Authors
Hosseini, Saeideh; Marandi, Farzin; Şahin, Ertan; Musevi, Seyid Javad
- Abstract
A new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and ¹H NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically "inactive" electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C-H⋯F, C-H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure.
- Subjects
CRYSTAL structure; THERMAL analysis; LEAD compounds synthesis; PHENANTHROLINE; TRIFLUOROACETIC acid; LIGANDS (Chemistry)
- Publication
Journal of Chemistry, 2013, p1
- ISSN
2090-9063
- Publication type
Article
- DOI
10.1155/2013/159125