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- Title
Phosphaindazole: A Phosphorus-Carbon Aromatic Heterocycle.
- Authors
Jevtovikj, Ivana; Sárosi, Menyhárt B.; Adhikari, Anup K.; Lönnecke, Peter; Hey‐Hawkins, Evamarie
- Abstract
A straightforward synthetic route to a novel phosphorus-carbon heterocycle, namely, phosphaindazole, which is the phosphorus analogue of indazole or indene, was developed from sodium tetraphosphanediide [Na2(P4Mes4)](Mes = 2,4,6-Me3C6H2) and nBuLi. A proposed intermediate in this reaction, the dimesityldiphosphanide dianion, could be isolated and structurally characterized as [Na8(thf)8(P2Mes2)4] ·2THF.
- Subjects
HETEROCYCLIC compounds synthesis; PHOSPHORUS compound synthesis; DENSITY functional theory; SOLID state chemistry; MOLECULAR structure
- Publication
European Journal of Inorganic Chemistry, 2015, Vol 2015, Issue 12, p2046
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201500172