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- Title
A Convergent Synthesis of the Tetrasaccharide Fragment of the Purported Structure of Durantanin I.
- Authors
Lee, Keehwan; Kim, Mijin; Rhee, Young Ho
- Abstract
A convergent synthesis of the tetrasaccharide subunit in the proposed structure of durantanin I is reported. The signature step is represented by the unique assembly of apiofuranoside ring by the sequential PdRu metal catalysis. Per‐dihydroxylation at the late stage delivered the target compound in a highly efficient manner. In addition, a tetrasaccharide derivative possessing unnatural apiose unit was also synthesized with comparable efficiency to that for the natural form.
- Subjects
CATALYSIS; METALS
- Publication
Bulletin of the Korean Chemical Society, 2021, Vol 42, Issue 4, p679
- ISSN
0253-2964
- Publication type
Article
- DOI
10.1002/bkcs.12265