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- Title
Structural and thermoanalytical characterization of self-healing polymer: the effect of cross-linking density.
- Authors
Takács, Tamás; Abdelghafour, Mohamed M.; Sebők, Dániel; Kukovecz, Ákos; Janovák, László
- Abstract
The effect of the gradually formed cross-linked structure on the thermal properties and swelling behaviour of modified poly(vinyl alcohol) was investigated. To this aim, the semi-crystalline polymer was functionalized with aldehyde and amino moieties to produce polymers with dynamic imine cross-links, and, thus, with self-healing or curing ability. With increasing degree of functionalization (0.89–7.12%), denser polymer networks cross-linked by dynamic imine bonds were formed, the samples systematically developed thermoset-like properties compared to the pristine, initially thermoplastic PVA. As a result, the introduction of new moieties into the initial PVA lowered the glass transition (from 65.3 to 35.0 °C) and melting temperatures (from 194 to 161 °C), however, a new peak (Tcrd) with growing enthalpy values appeared on the DSC curves, which indicates that more and more energy must be supplied in order to break the imine cross-links formed between the introduced aldehyde and amino groups. The significant impact of the degree of functionalization and cross-linking density on the polymer structure was also clearly demonstrated: the crystallinity decreased as the abundance of the introduced moieties increased and the formation of cross-links proceeded. At the same time, the water desorption enthalpies of the samples increased, suggesting a stronger, chemically cross-linked thermoset-like polymer network compared to the thermoplastic poly(vinyl alcohol).
- Subjects
SELF-healing materials; POLYMER networks; CROSSLINKED polymers; POLYMER structure; AMINO group; GLASS transitions; MOIETIES (Chemistry)
- Publication
Journal of Thermal Analysis & Calorimetry, 2024, Vol 149, Issue 7, p2765
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-023-12862-2