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- Title
Cationic-Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent.
- Authors
REN, Kai; Zhang, Lei; Hu, Bei; Zhao, MENgmENg; Tu, Yahui; Xie, Xiaomin; Zhang, Tony Y.; Zhang, Zhaoguo
- Abstract
On the [Rh]oad again: A series of optically pure allylic alcohols is obtained through the Rh/BINAP ‐ catalyzed redox isomerization of racemic allylic alcohols. An improved system involves the use of cationic rhodium and a noncoordinating solvENt, in which aromatic and aliphatic allylic alcohols are effectively resolved with kf/ks (kf=rate of fast reaction, ks=rate of slow reaction) values up to 24.
- Subjects
CATALYTIC isomerization; ALLYL alcohol; CARBONYL compounds; RHODIUM catalysts; ISOMERIZATION; SOLVENTS; CATALYSTS; LIGANDS (Chemistry)
- Publication
ChemCatChem, 2013, Vol 5, Issue 6, p1317
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201300014