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- Title
New three-component reaction of perimidines with sodium azide and sodium nitrite in polyphosphoric acid.
- Authors
Lyakhovnenko, A.; Aksenov, A.; Aksenov, N.; Goncharov, V.; Aksenova, I.
- Abstract
The article discusses the development of a method for peri-annelation of pyrrole and furan rings to naphthalene derivatives. It mentions that the method is based on electrophilic amination of arenes in polyphosphoric acid and nitrosation of the heterocyclic intermediates. It notes that the perimidines are heated with sodium azide and sodium nitrite. It also emphasizes that the mechanism for the reaction involves the formation of the intermediate compounds from the perimidines and sodium azide.
- Subjects
PYRROLES; FURANS; NAPHTHALENE derivatives; POLYPHOSPHORIC acid; NITROSATION; SODIUM azide; SODIUM nitrites
- Publication
Chemistry of Heterocyclic Compounds, 2012, Vol 48, Issue 4, p677
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1007/s10593-012-1043-x