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- Title
Robust Single Molecule Magnet Monolayers on Graphene and Graphite with Magnetic Hysteresis up to 28 K.
- Authors
Spree, Lukas; Liu, Fupin; Neu, Volker; Rosenkranz, Marco; Velkos, Georgios; Wang, Yaofeng; Schiemenz, Sandra; Dreiser, Jan; Gargiani, Pierluigi; Valvidares, Manuel; Chen, Chia‐Hsiang; Büchner, Bernd; Avdoshenko, Stanislav M.; Popov, Alexey A.
- Abstract
The chemical functionalization of fullerene single molecule magnet Tb2@C80(CH2Ph) enables the facile preparation of robust monolayers on graphene and highly oriented pyrolytic graphite from solution without impairing their magnetic properties. Monolayers of endohedral fullerene functionalized with pyrene exhibit magnetic bistability up to a temperature of 28 K. The use of pyrene terminated linker molecules opens the way to devise integration of spin carrying units encapsulated by fullerene cages on graphitic substrates, be it single‐molecule magnets or qubit candidates.
- Subjects
SINGLE molecule magnets; PYROLYTIC graphite; MAGNETIC hysteresis; MONOMOLECULAR films; GRAPHITE; GRAPHENE
- Publication
Advanced Functional Materials, 2021, Vol 31, Issue 48, p1
- ISSN
1616-301X
- Publication type
Article
- DOI
10.1002/adfm.202105516