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- Title
Reversible modulation of interlayer stacking in 2D copper-organic frameworks for tailoring porosity and photocatalytic activity.
- Authors
You, Pei-Ye; Mo, Kai-Ming; Wang, Yu-Mei; Gao, Qiang; Lin, Xiao-Chun; Lin, Jia-Tong; Xie, Mo; Wei, Rong-Jia; Ning, Guo-Hong; Li, Dan
- Abstract
The properties of two-dimensional covalent organic frameworks (2D COFs), including porosity, catalytic activity as well as electronic and optical properties, are greatly affected by their interlayer stacking structures. However, the precise control of their interlayer stacking mode, especially in a reversible fashion, is a long-standing and challenging pursuit. Herein, we prepare three 2D copper-organic frameworks, namely JNM-n (n = 7, 8, and 9). Interestingly, the reversible interlayer sliding between eclipsed AA stacking (i.e., JNM-7-AA and JNM-8-AA) and staggered ABC stacking (i.e., JNM-7-ABC and JNM-8-ABC) can be achieved through environmental stimulation, which endows reversible encapsulation and release of lipase. Importantly, JNM-7-AA and JNM-8-AA exhibit a broader light absorption range, higher charge-separation efficiency, and higher photocatalytic activity for sensitizing O2 to 1O2 and O2•− than their ABC stacking isostructures. Consequently, JNM-8-AA deliver significantly enhanced photocatalytic activities for oxidative cross-coupling reactions compared to JNM-8-ABC and other reported homogeneous and heterogeneous catalysts. The precise control of interlayer stacking mode of 2D materials is a long-standing pursuit. Here, the authors report two 2D copper-organic frameworks that can undergo the reversible interlayer sliding through environmental stimulation.
- Subjects
CATALYTIC activity; POROSITY; LIGHT absorption; COPPER catalysts; HETEROGENEOUS catalysts; OPTICAL properties; PHOTOCATALYSTS; LIPASES
- Publication
Nature Communications, 2024, Vol 15, Issue 1, p1
- ISSN
2041-1723
- Publication type
Article
- DOI
10.1038/s41467-023-44552-w