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- Title
IN SITU CRYSTALLIZATION AND CRYSTAL STRUCTURE DETERMINATION OF CHLOROBENZENE.
- Authors
Nath, Naba K.; Naumov, Panče
- Abstract
The crystal structure of chlorobenzene, which is liquid at ambient conditions of pressure and temperature, was determined after in situ crystallization by using Optical Heating and Crystallization Device (OHCD) coupled to a single crystal X-ray diffractometer. Chlorobenzene crystallizes in the orthorhombic space group Pbcn with one symmetry-independent molecule in the asymmetric unit. In the crystal structure, type II Cl⋯Cl interactions form zigzag chains that are assisted by C--H⋯π interactions. Hirshfeld surface analysis revealed five types of intermolecular contacts.
- Subjects
CRYSTALLIZATION; CRYSTAL structure; X-ray diffraction; CHLOROBENZENE; HEATING; TEMPERATURE effect; HALOGENS
- Publication
Macedonian Journal of Chemistry & Chemical Engineering, 2015, Vol 34, Issue 1, p1
- ISSN
1857-5552
- Publication type
Article
- DOI
10.20450/mjcce.2015.682