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- Title
Template‐free Electrosynthesis of Platinum Nano‐Cauliflowers for Catalysing Electron Transfer Reaction of Plutonium.
- Authors
Ambolikar, Arvind S.; Guin, Saurav K.
- Abstract
A coupled‐oxido‐reductive multiple‐potentiostatic pulse strategy was developed to electrochemically prepare platinum‐nano‐cauliflowers (PtNCFs) on indium‐tin‐oxide (ITO) coated glass electrode. The mechanism of electrocrystallization was studied during the formation of PtNCFs on ITO. By virtue of that synthesis strategy, the PtNCFs/ITO surface could catalyse the quasi‐reversible electron transfer reaction of plutonium (Pu) (IV)/(III) redox couple in aqueous sulphuric acid solution compared to bare ITO.
- Subjects
OXIDATION-reduction reaction; ELECTROSYNTHESIS; PLUTONIUM; PLATINUM; GLASS electrodes; SULFURIC acid; ELECTROCRYSTALLIZATION
- Publication
Electroanalysis, 2020, Vol 32, Issue 11, p2503
- ISSN
1040-0397
- Publication type
Article
- DOI
10.1002/elan.202060058