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- Title
New Insights into the Mechanism of Reduction of Tertiary Phosphine Oxides by Means of Phenylsilane.
- Authors
Demchuk, Oleg M.; Jasiński, Radomir; Pietrusiewicz, K. Michał
- Abstract
The mechanism of the reduction of phosphine oxides by PhSiH3 was established on the basis of kinetic measurements and Density Functional Theory (DFT) calculations. In particular, it has been proved that the model reaction between tri-nbutylphosphine oxide and phenylsilane occurs via a nonpolar mechanism. The data presented herein allow prediction and verification of the applicability of the new reduction reagents and conditions for industrially attractive processes.
- Subjects
CHEMICAL reduction; TERTIARY structure; PHOSPHINE oxides; SILANE compounds; DENSITY functional theory
- Publication
Heteroatom Chemistry, 2015, Vol 26, Issue 6, p441
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/hc.21279