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- Title
Synthesis and Catalytic Activity of the Fe(II) and Fe(III) Complexes with a New Polydentate Ligand Containing an Amide Donor.
- Authors
Gutkina, E. A.; Rubtsova, T. B.; Shteinman, A. A.
- Abstract
The iron complexes [Fe2+(tpcaH)(MeCN)2](ClO4)2 (I) and [Fe2O(tpca)2(H2O)2](ClO4)2 (II) based on the new potentially tetradentate ligand bis(2-pyridyl)methyl-2-pyridylcarboxamide (tpcaH) with the amide donor group inside the molecule were synthesized. The composition of the complexes was confirmed by elemental and mass spectrometric analyses and various spectral methods. Compounds I and II exhibited good catalytic activity in the stereospecific oxidation of alkanes by hydrogen peroxide.
- Subjects
IRON; HYDROGEN peroxide; LIGANDS (Chemistry); CHEMICAL elements; CATALYSIS; PHYSICAL &; theoretical chemistry
- Publication
Kinetics & Catalysis, 2003, Vol 44, Issue 1, p106
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1023/A:1022580903767