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- Title
Radical Reactions of 1,4-Bis(vinylsulfonyl)tetrafluorobenzene with Tetrahydrofuran.
- Authors
Amosova, S. V.; Gavrilova, G. M.
- Abstract
Homolytic addition of tetrahydrofuran at the vinylsulfonyl groups of 1,4-bis(vinylsulfonyl)tetrafluorobenzene in the absence of radical initiator at 20 and 55°C leads to formation of 1,4-bis[2-(2-tetrahydrofuryl)ethylsulfonyl]tetrafluorobenzene in 16 and 42% yield, respectively, and a mixture of telomers. The latter are formed as a result of opening of the tetrahydrofuran ring in the adduct.
- Subjects
TETRAHYDROFURAN; FREE radical reactions; CHEMICAL reactions; FREE radicals; FURANS; HETEROCYCLIC compounds
- Publication
Russian Journal of Organic Chemistry, 2003, Vol 39, Issue 5, p705
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1023/A:1026069515085