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- Title
Amino‐Supported Palladium Catalyst for Chemo‐ and Stereoselective Domino Reactions.
- Authors
Li, Man‐Bo; Yang, Jie; Yang, Ying; Xu, Guo‐Yong; Luo, Gen; Yang, Jianping; Bäckvall, Jan‐E.
- Abstract
A solid amino‐supported palladium catalyst is used in an oxidative domino reaction for the diastereoselective construction of alkyne‐substituted cyclopentenol compounds. This heterogeneous catalyst exhibits high efficiency and excellent chemoselectivity, as well as good recyclability. The chemoselectivity of the domino reactions was readily controlled by switching the solvent and catalyst. Asymmetric syntheses and an oxidative carbocyclization‐borylation reaction have also been developed based on the heterogeneous palladium catalyst.
- Subjects
STEREOSELECTIVE reactions; ASYMMETRIC synthesis; HETEROGENEOUS catalysis; CATALYST supports; CHEMOSELECTIVITY; PALLADIUM catalysts; HETEROGENEOUS catalysts
- Publication
Angewandte Chemie, 2021, Vol 133, Issue 2, p680
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202011708