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- Title
Crystal structure and theoretical investigation of bis(cis-1,2-diaminocyclohexane)zinc(II) tetrachloridozincate(II).
- Authors
Akhtar, Muhammad; Zierkiewicz, Wiktor; Michalczyk, Mariusz; Rüffer, Tobias; Lang, Heinrich; Isab, Anvarhusein A.; Mazhar, Muhammad; Ahmad, Saeed
- Abstract
A zinc(II) complex of cis-1,2-diaminocyclohexane (Dach), [Zn(Dach)2][ZnCl4] (1), was prepared and its structure was determined by X-ray crystallography. Theoretical (density functional theory) studies were performed for the two model compounds, [Zn(Dach)2][ZnCl4] (1) and {[Zn(Dach)2][ZnCl4]}3 (13). The structure of complex 1 is composed of [Zn(Dach)2]2+ cations and [ZnCl4]2- anions. The Zn1 atom in the cationic complex adopts a severely distorted tetrahedral geometry, while in the anionic part, Zn2 displays only a slight distortion from tetrahedral coordination. The adjacent cations and anions are associated with each other through hydrogen bonding interactions to form a two-dimensional network in the solid state.
- Subjects
CRYSTAL structure; CRYSTALLOGRAPHY; PHENYLENEDIAMINES; TETRACHLORODIBENZODIOXIN; CATIONIC polymers
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2017, Vol 72, Issue 8, p627
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2017-0006