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- Title
Decarboxylative Amination with Nitroarenes via Synergistic Catalysis<sup>†</sup>.
- Authors
Ding, Meiling; Zhou, Sitian; Yao, Shunruo; Zhu, Chengjian; Li, Weipeng; Xie, Jin
- Abstract
Comprehensive Summary: In this paper, we have developed a decarboxylative amination of carboxylic acids with nitroarenes for the synthesis of secondary amines. The protocol is performed at mild conditions without the use of noble metals as catalysts. A wide range of structurally diverse secondary amines could be obtained in good yields (up to 94%) with good functional group tolerance. This transformation shows good to excellent selectivity, avoiding the generation of over alkylated byproducts.
- Subjects
NITROAROMATIC compounds; CARBOXYLIC acids; AMINATION; SECONDARY amines; PRECIOUS metals; METAL catalysts
- Publication
Chinese Journal of Chemistry, 2024, Vol 42, Issue 4, p351
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.202300493