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- Title
Crosslinking polymerization of polyfunctional monomers by free radical mechanism.
- Authors
Vlad, Cristina Doina; Vasiliu, Silvia
- Abstract
The crosslinked architectures based on diallyl maleate (DAM) obtained by suspension polymerization techniques have been studied. The influence of synthesis parameters on the structure of poly(diallyl maleate) [poly(DAM)] and copolymers of DAM with methyl methacrylate (MM) [poly(DAM-co-MM)] was also investigated. The effect of the diluents (n-butyl acetate or cyclohexanole) on the inner macroporous structure (apparent and skeletal density, pore volume, total porosity, cyclohexane uptake) has been studied. The experimental results showed that the values of the solvent uptake are strongly influenced by the diluent quantity as well as its solubility parameter.
- Subjects
CROSSLINKING (Polymerization); POLYMERIZATION; FREE radicals; MONOMERS; METHYL methacrylate; CYCLOHEXANE; SOLUTION (Chemistry)
- Publication
Polimery, 2010, Vol 55, Issue 3, p181
- ISSN
0032-2725
- Publication type
Article
- DOI
10.14314/polimery.2010.181