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- Title
Rhodium‐Catalyzed Stitching Polymerization of 1,5‐Hexadiynes and Related Oligoalkynes.
- Authors
Ikeda, Sho; Shintani, Ryo
- Abstract
A new mode of polymerization, rhodium‐catalyzed stitching polymerization, has been developed for the synthesis of π‐conjugated polymers with bridged repeating units from nonconjugated 1,5‐hexadiynes containing both terminal and internal alkyne moieties as monomers. The polymerization proceeded smoothly with a high degree of stitching efficiency under mild conditions, and 1,5,9‐decatriyne and 1,5,9,13‐tetradecatetrayne monomers could also be employed. The present polymerization strategy would be particularly beneficial for the synthesis of polymers consisting of a repeating unit that is difficult to prepare as a stable monomer because it does not require the use of a preformed bridged π‐conjugated monomer.
- Subjects
RHODIUM; HEXADIYNE; ALKYNES; POLYMERIZATION; MONOMERS
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 17, p5790
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201901148