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- Title
Comparative Study of Redox Reactions of Aqua- and Thiocyanatocobalamin.
- Authors
Salnikov, D. S.; Makarov, S. V.; Ivlev, P. A.
- Abstract
The interaction of aqua- and thiocyanatocobalamin with sodium hydroxymethanesulfinate in neutral aqueous solution has been studied, and the kinetic as well as activation parameters of the reactions have been determined. The reduction of the aqua complex is faster in comparison with the thiocyanato one. In contrast to the earlier studied reaction of hydroxymethanesulfinate with cyanocobalamin, reduction of aquaand thiocycnatocobalamins occurs via the associative mechanism.
- Subjects
OXIDATION-reduction reaction; VITAMIN B12; SPECTROPHOTOMETRY; AQUEOUS solutions; CHEMICAL reactions
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 5, p958
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218050201