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- Title
Photoassisted Oxidation of Sulfides Catalyzed by Artificial Metalloenzymes Using Water as an Oxygen Source.
- Authors
Herrero, Christian; Nguyen-Thi, Nhung; Hammerer, Fabien; Banse, Frédéric; Gagné, Donald; Doucet, Nicolas; Mahy, Jean-Pierre; Ricoux, Rémy
- Abstract
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-tetrakis(p-carboxyphenyl)porphyrin [Mn(TpCPP), 1-Mn] into xylanase 10A from Streptomyces lividans (Xln10A) as a host protein, was found able to catalyze the selective photo-induced oxidation of organic substrates in the presence of [RuΠ(bpy)3]2+ as a photosensitizer and[Coш(NH3)5 Cl]2+as a sacrificial electron acceptor, using water as oxygen atom source.
- Subjects
PHOTOOXIDATION; OXIDATION of sulfides; METALLOENZYMES
- Publication
Catalysts (2073-4344), 2016, Vol 6, Issue 12, p202
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal6120202