We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
High‐pressure/High‐temperature Synthesis of ErCd<sub>2</sub>B<sub>7</sub>O<sub>13</sub>(BO(OH)<sub>3</sub>): A Non‐centrosymmetric Erbium Cadmium Borate.
- Authors
Teichtmeister, Tobias A.; Schwarzmüller, Stefan; Huppertz, Hubert
- Abstract
Explorative high‐pressure/high‐temperature syntheses (7 GPa, 800 °C) starting from Er2O3, CdO, and H3BO3 yielded single‐crystals of the hitherto unknown compound ErCd2B7O13(BO(OH)3). This compound crystallizes trigonally in the non‐centrosymmetric space group R3c with the unit cell parameters a=8.8418(2) Å, c=22.4972(8) Å, and six formula units per cell. The crystal structure is composed of corner‐sharing trigonal planar [BO3] and tetrahedral [BO4] groups, forming a complex three‐dimensional framework. In this article, the structural data and characteristics of ErCd2B7O13(BO(OH)3) are presented in detail. Furthermore, the compound's infrared spectrum is discussed.
- Subjects
CADMIUM crystals; UNIT cell; CRYSTAL structure; SPACE groups; INFRARED spectra
- Publication
European Journal of Inorganic Chemistry, 2024, Vol 27, Issue 24, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202400211