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- Title
Towards Molecular Construction Platforms: Synthesis of a Metallotricyclic Spirane Based on Bis(2,2′:6′,2'-Terpyridine)Ru<sup>II</sup> Connectivity.
- Authors
Xie, Ting‐Zheng; Guo, Kai; Huang, Mingjun; Lu, Xiaocun; Liao, Sheng‐Yun; Sarkar, Rajarshi; Moorefield, Charles N.; Cheng, Stephen Z. D.; Wesdemiotis, Chrys; Newkome, George R.
- Abstract
The design and construction of the first multicomponent stepwise assembly of a <tpy-RuII-tpy>-based (tpy=terpyridine), three-dimensional, propeller-shaped trismacrocycle, 8, are reported. Key steps in the synthesis involve the preparation of a hexaterpyridinyl triptycene and its reaction with dimeric, 60°-directional, bisterpyridine-RuII building blocks. Characterization includes ESI- and ESI-TWIM-MS and TEM, along with 1D and 2D 1H NMR spectroscopy.
- Subjects
MOLECULAR structure; TRIPTYCENES; CHEMICAL synthesis; NUCLEAR magnetic resonance spectroscopy; REACTION mechanisms (Chemistry)
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 36, p11291
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201403840